Basis for original (SCP): IDLH AIHA [1958] reported that rats exposed repeatedly to about 10 ppm for 4 hours daily died, whereas those exposed to about 0.1 ppm, 5 hours daily for 10 weeks, showed no detectable effects [Dalhamn 1957]. AIHA [1958] also reported that animals survived 2hour exposures to 20 ppm, though some species exhibited symptoms [Gloemme and Lundgren 1957]. Elkins [1950] stated that 5 ppm is definitely irritating and 2 cases of illness (1 fatal) resulted from exposure to less than 19 ppm. AIHA [1958] reported that delayed deaths occur in animals after single exposures to 150 to 200 ppm for less than 1 hour [Gloemme and Lundgren 1957]. Based on the data cited above, an IDLH of 10 ppm is chosen.
Human data: It has been reported that 5 ppm is definitely irritating and that 19 ppm caused the death of one worker inside a tank (time of exposure was not specified) [Elkins 1950].
Revised IDLH: 5 ppm
Basis for revised IDLH: The revised IDLH is 5 ppm based on acute inhalation toxicity data in humans [Elkins 1950].